Geological Society of America

T52 Pyrogenic Black Carbon, or Biochar, in Soils and Sediments, Its Characterization and Fate, Its Effects on the Carbon Cycle and Carbon Sequestration, and Its Effects on Soil Properties (Posters)

Sunday, 27 October 2013
9:00 AM - 6:30 PM
Hall D

BIOCHAR PHYSICAL PROPERTIES ARE KEY TO UNDERSTANDING ENVIRONMENTAL PERFORMANCE

Paper number: T52-3
Program: Technical Sessions
Time: 9:00 AM – 6:30 PM

Authors

Caroline A. Masiello Presenting Author
Rice University, Houston, TX
Lacey A. Pyle
Rice University, Houston, TX
Catherine Brewer
New Mexico State University, Las Cruces, NM
Brandon Dugan
Rice University, Houston, TX
Zuolin Liu
Rice University, Houston, TX
Helge Gonnermann
Rice University, Houston, TX
Kyriacos Zygourakis
Rice University, Houston, TX
Xiaodong Gao
Rice University, Houston, TX
Christian A. Davies
Shell International Exploration and Production, Inc, Houston, TX
Pietro Panzacchi
University of Bologna, Bologna, N/A

Abstract

Some of the most sought-after biochar environmental effects are a result of its physical characteristics, not its chemical or biological properties. For example, the ability of biochar to retain soil water is widely attributed to its internal porosity. However, biochar physical properties are so poorly understood that they are sometimes not characterized at all in the current literature.

Here we outline a suite of basic physical properties of biochar and the likely environmental effects of their variations, with a focus on the interactions between biochar and water. The most basic physical property of biochar, its particle size, likely plays a role in biochar’s ability to alter the rate of drainage in soils. Particle morphology is also relevant, affecting how particles of soil and char can pack together. Bulk densities of biochar and soil mixtures can be used to generate a simple estimate of the efficiency of char-soil packing.

Biochar density is an additionally important property and can be measured in a number of ways. Density almost certainly controls the tendency of chars to sink or float, and to erode or remain on the land surface. However, biochar density can vary by almost a factor of 10 depending on the measurement technique used. We discuss two simple techniques available for measuring char density and the value of information provided by each approach.

Finally, we report a simple, fast technique to measure total char porosity, including all pores from nanometers to 10s of micrometers in size. Porosity is at least one of the key controls on the ability of biochar to improve plant-available water, and techniques to measure it have previously been limited to the smallest fraction of pores (N₂ sorption) or have required expensive, hazardous procedures (Hg porosimetry). We show that char porosity varies primarily as a function of feedstock and secondarily as a function of pyrolysis conditions.