T8 Evolution of the Western Interior Basin: New Advances and Fresh Perspectives
Sunday, 15 October 2023
8:00 AM - 12:00 PM
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APPLICATION OF SULFUR ISOTOPE RECORDS TO THE RECONSTRUCTION OF RELATIVE SEA LEVEL CHANGES IN THE LATE CRETACEOUS WESTERN INTERIOR SEAWAY
Paper number: T8-10
Program: Technical Sessions
Time: 10:05 AM – 10:20 AM
Authors
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Matthew T. HurtgenNorthwestern University, Evanston, IL
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Andrew L. MastersonNorthwestern University, Evanston, IL
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Jordan TodesUniversity of Chicago, Chicago, IL
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Bradley SagemanNorthwestern University, Evanston, IL
Abstract
Building on prior studies that established detailed litho-, bio-, and chemostratigraphic frameworks for the Cenomanian-Turonian Greenhorn Cyclothem, and the Coniacian-Campanian Niobrara Cyclothem, we examine the relationship between changes in RSL and offshore (fine-grained) sediment supply using a relatively new proxy: the isotopic composition of authigenic pyrite sulfur (δ34Spyr). The basis for this proxy, recently applied to Pleistocene and Holocene sediments, is derived from the influence of sedimentation rate upon the early diagenesis of organic carbon by sulfate reduction, with sulfide ultimately captured in sedimentary pyrite. High rates of sedimentation (regressions) isolate pore waters more rapidly, resulting in a reservoir effect that drives progressively heavier δ34Spy values, whereas decreased supply of fine-grained sediment (transgressions) allows fractionation to approach theoretical limits (~70‰), resulting in much more negative d34Spyr values. Testing this hypothesis at two different scales – the short-term (parasequence) scale and the long-term (cyclothem) scale, we observe clear evidence for consistent negative d34Spyr excursions during transgressive episodes, and a less pronounced effect in progressively more distal sites where the sedimentation rate contrast is less pronounced.
Geological Society of America Abstracts with Programs. Vol. 55, No. 6
doi: 10.1130/abs/2023AM-395479
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