T113 Weathering, Sedimentation, and Diagenesis in Major Element Cycles II: In Memory of Raymond Siever
Monday, 17 October 2005
1:30 PM - 3:30 PM
ORIGIN OF ASSOCIATED TERRA ROSSA AND KARST BY REPLACEMENT
Paper number: T113-3
Program: Technical Sessions
Time: 1:50 PM – 2:05 PM
Authors
Abstract
The iron, aluminum, and silicon needed for clay growth are provided probably by dust. (Saharan dust is abundant in the Caribbean and southern Europe.) The dust dissolves at the surface, the solutes leak in, reach the reaction front several feet deep, and precipitate to make the red clay crystals that replace the limestone. Terra rossa is thus a unique laterite – one none of whose major elements comes from its parent limestone, and one that supports wineries.
The volume-adjusted replacement of limestone by clay produces acid. This acid dissolves voids just ahead of the reaction zone. The new porosity propels advection of solutes to the reaction zone. This accelerates further replacement, which in turn produces more acid. Through this feedback – the reactive-infiltration instability, modeled in the 80s – a planar dissolution front should become a set of regularly spaced funnels: This is how karst forms. The terra rossa is thus not an alluvial mud that gets trapped in preexisting karst funnels or sinks, as traditionally held. Terra rossa, as it replaces limestone, carves the very karst that contains it. That is why the two are associated.